The section you highlighted ($b[$_],$b[$i] = $b[$i],$b[$_]) will swap two values in array $b: the one at index $_ with the one at index $i.
Also for reference if others are curious, this snippet comes from here: https://gist.github.com/AndrewSav/6102160. Just because it’s in a function to decrypt some data though doesn’t mean it has to be quite so cryptic.
Below is another version of the same script, expanded out a little. I haven’t tried it but I believe it will do the same thing.
for ($i = $j = 0; $i -lt 256; $i++) { # I didn’t figure out what keySeed and b were for, so I can’t really comment on this line $j += $b[$i] + $keySeed[$i] # Make sure $j is less than or equal to 255 (0xff) by stripping off the higher bits so that it continues to be a valid index into our array $j = $j -band 0xff # Swap $b[$i] with $b[$j] $b[$i],$b[$j] = $b[$j],$b[$i] }